Steam methane reforming reaction process intensification by using a millistructured reactor: Experimental setup and model validation for global kinetic reaction rate estimation
Identifieur interne : 000921 ( Main/Exploration ); précédent : 000920; suivant : 000922Steam methane reforming reaction process intensification by using a millistructured reactor: Experimental setup and model validation for global kinetic reaction rate estimation
Auteurs : M. Mbodjim [France] ; J. M. Commenge [France] ; Laurent Falk [France] ; D. Di Marco [France] ; F. Rossignol [France] ; L. Prost [France] ; S. Valentin [France] ; R. Joly [France] ; P. Del-Gallo [France]Source :
- Chemical engineering journal : (1996) [ 1385-8947 ] ; 2012.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Rendement énergétique.
English descriptors
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Abstract
In the frame of steam methane reforming process intensification, a highly active and stable catalyst based on rhodium with catalyst formulation and structure adapted to millistructured reactors has been formulated. This catalyst has been tested in industrial conditions (800, 850 or 900 °C and 20 bars) on a single channel which is representative of one channel of a more complex millistructured SMR reactor. Then, a detailed mathematical model for acquisition of the global reaction kinetics with this new catalyst has been developed and validated from experimental catalytic tests. The developed kinetics is dependent of the catalyst microstructure. This study presents the set-up, the model, the experimental catalytic runs and the global kinetics estimation protocol. It demonstrates, on one hand, that millistructured reactor is suitable for kinetic data acquisition and, on the other hand, the possibility of SMR process intensification, for improved energy efficiency and process size reduction.
Affiliations:
- France
- Grand Est, Limousin, Lorraine (région), Nouvelle-Aquitaine, Île-de-France
- Jouy-En-Josas, Limoges, NANCY, Nancy
- Centre national de la recherche scientifique, Laboratoire réactions et génie des procédés, Université de Lorraine
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Joly</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Air Liquide, Centre de Recherche Claude & Delorme, 1 chemin de la porte des Loges, BP 126</s1><s2>78354 Jouy-En-Josas</s2><s3>FRA</s3><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Jouy-En-Josas</settlement></placeName></affiliation></author><author><name sortKey="Del Gallo, P" sort="Del Gallo, P" uniqKey="Del Gallo P" first="P." last="Del-Gallo">P. Del-Gallo</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Air Liquide, Centre de Recherche Claude & Delorme, 1 chemin de la porte des Loges, BP 126</s1><s2>78354 Jouy-En-Josas</s2><s3>FRA</s3><sZ>6 aut.</sZ><sZ>7 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Jouy-En-Josas</settlement></placeName></affiliation></author></analytic><series><title level="j" type="main">Chemical engineering journal : (1996)</title><title level="j" type="abbreviated">Chem. eng. j. : (1996)</title><idno type="ISSN">1385-8947</idno><imprint><date when="2012">2012</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Chemical engineering journal : (1996)</title><title level="j" type="abbreviated">Chem. eng. j. : (1996)</title><idno type="ISSN">1385-8947</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Catalyst</term><term>Catalytic reaction</term><term>Data acquisition</term><term>Energetic efficiency</term><term>Kinetics</term><term>Mathematical model</term><term>Microreactor</term><term>Microstructure</term><term>Modeling</term><term>Reaction rate</term><term>Reactor</term><term>Reforming</term><term>Synthesis gas</term><term>Water vapor</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Vapeur eau</term><term>Reformage</term><term>Réacteur</term><term>Modélisation</term><term>Cinétique</term><term>Vitesse réaction</term><term>Catalyseur</term><term>Modèle mathématique</term><term>Réaction catalytique</term><term>Microstructure</term><term>Saisie donnée</term><term>Rendement énergétique</term><term>Gaz synthèse</term><term>Microréacteur</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Rendement énergétique</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">In the frame of steam methane reforming process intensification, a highly active and stable catalyst based on rhodium with catalyst formulation and structure adapted to millistructured reactors has been formulated. This catalyst has been tested in industrial conditions (800, 850 or 900 °C and 20 bars) on a single channel which is representative of one channel of a more complex millistructured SMR reactor. Then, a detailed mathematical model for acquisition of the global reaction kinetics with this new catalyst has been developed and validated from experimental catalytic tests. The developed kinetics is dependent of the catalyst microstructure. This study presents the set-up, the model, the experimental catalytic runs and the global kinetics estimation protocol. It demonstrates, on one hand, that millistructured reactor is suitable for kinetic data acquisition and, on the other hand, the possibility of SMR process intensification, for improved energy efficiency and process size reduction.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Grand Est</li><li>Limousin</li><li>Lorraine (région)</li><li>Nouvelle-Aquitaine</li><li>Île-de-France</li></region><settlement><li>Jouy-En-Josas</li><li>Limoges</li><li>NANCY</li><li>Nancy</li></settlement><orgName><li>Centre national de la recherche scientifique</li><li>Laboratoire réactions et génie des procédés</li><li>Université de Lorraine</li></orgName></list><tree><country name="France"><region name="Grand Est"><name sortKey="Mbodjim, M" sort="Mbodjim, M" uniqKey="Mbodjim M" first="M." last="Mbodjim">M. Mbodjim</name></region><name sortKey="Commenge, J M" sort="Commenge, J M" uniqKey="Commenge J" first="J. M." last="Commenge">J. M. Commenge</name><name sortKey="Del Gallo, P" sort="Del Gallo, P" uniqKey="Del Gallo P" first="P." last="Del-Gallo">P. Del-Gallo</name><name sortKey="Di Marco, D" sort="Di Marco, D" uniqKey="Di Marco D" first="D." last="Di Marco">D. Di Marco</name><name sortKey="Falk, L" sort="Falk, L" uniqKey="Falk L" first="L." last="Falk">Laurent Falk</name><name sortKey="Joly, R" sort="Joly, R" uniqKey="Joly R" first="R." last="Joly">R. Joly</name><name sortKey="Prost, L" sort="Prost, L" uniqKey="Prost L" first="L." last="Prost">L. Prost</name><name sortKey="Rossignol, F" sort="Rossignol, F" uniqKey="Rossignol F" first="F." last="Rossignol">F. Rossignol</name><name sortKey="Valentin, S" sort="Valentin, S" uniqKey="Valentin S" first="S." last="Valentin">S. Valentin</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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